Standing Order Correct Way

Please can you tell me the correct way to add a Standing Order with my bank that will get it into T212 instantly after it has been setup.

What do i need to add to identify the correct part of my account ?

Go to the deposit section in the app and select bank transfer to get your details. Try it with say a quid, sometimes takes a day to show up.

I was looking at setting up a daily invest into a pie using auto investment